Parsing .exe files
For a GUI app that parses an app's exe file I've used NPE File Analyzer for years. Sadly the app is no longer being developed, at least not for free.
It works just fine on Win10 x64 Pro, so likely to not have any agita
The PE parsing library referenced above looks nice, the prebuilt app sends Win10 into a tizzy about an unknown publisher. PFFFFFFFFFFFFFFFFFFFFT!