Getting started with sending email with C++

VMime is for this work. The thing is that I dont have idea how to use it. Can anyone help me a bit with this? thank you!
My idea is to build a GUI program that the user gives gmail/hotmail/yahoo/AOL (he selects this in a combobox) his passwd, title and body of the message, receiver and a button which says send.. I know to build GUI programs and but i dont know how to use vmime, that's the only issue! If anyone knows a good tut, or can describe shortly how to use it, I would be grateful!
Mail is sent using SMTP. You need to understand that first.
http://lmgtfy.com/?q=rfc+smtp
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