Structured Query Language.
It's not a relational database, but a way to communicate with them.
First of all, be aware of the model. Understand primary and foreign keys, and how do you map relationships to tables.
Then learn the language.
_ queries (where, inner join)
_ table creation and update (constraints)
_ aggregate queries (count, avg, ..., group by, having)
_ transactions (rollback)
Later you will need triggers, but that is coupled with the engine that you use.
Also take a look at what SQL injection is.
http://xkcd.com/327/