This is a c++ board. Your code, while valid c++ in the sense that it compiles, is in fact more c than it is c++. I suggest that you get a book like the "C++ Primer" or "The C++ Programming Language" (beware, it was published before the standard and has some flaws, however, if you want the standard, get the standard, this book is still great). To your problem:
5: it is not main(), it is int main()
9: printf is a c function, use operator<<
10: scanf is a c function, use operator>>, in combination with std::stringstream if needed
12: What a statement. Why not check a<0 and omit the else block?
13: b is not initialized. It's value is undefined.
While not trying to overrule my friend up here, I want to provide a shorter solution:
Replace #include <stdio.h> with #include <cstdio>
Remove #include <conio.h>, and never use it again. Ever.
Replace main() with int main()
Do not declare b. You're not using it.
Replace
1 2 3
if (a>0)
a=a;
else a=-b;
with
1 2
if (a<0)
a=-a;
You're done.
Oh, and don't use expressions such as a=a. While that doesn't have much of an effect on primitives, objects may not be so forgiving, and using expressions like that might consume ridiculous amounts of time.