Your title is a little confusing. But, if you have a sentence as your input, you could:
1 2 3 4 5 6 7
Read in the sentence
Start at the end of the sentence:
Look at each character
When the character is a space,
You know the previous character is the character you want.
@fahmankhan75 Strings and cstrings( character arrays ) work the same. You can access the first element ( first letter ) by using the operator[] so you would call it like this mystring[0];