Only one constructor will be used, it's up to you to choose it.
To use a different constructor, you do something like this, where the arguments types, and order match the parameters of the constructor you wish to call.
Employee dwight("Dwight K. Schrute", "sales", "salesman and assistant to the regional manager");
If you leave out an explicit call to the constructor, as in Employee dwight;, then the default constructor, the one with no parameters, is called implicitly.