They are equivalent, but most people will use [] for arrays because it makes it immediately clear you are accessing an array instead of possibly just dereferencing a normal pointer.
In this case it works the same, but there is many other cases where behavior of there operations is completely different.
It is important to save semantic: Do you dereferencing pointer to char which points to desired letter, or you are selecting array element?
Choosing right operator will improve readability and can save you frome some errors.
Example
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char* x = find(someCString, 'a');
std::cout << *x << std::endl; //dereferencing pointer to found character
char* y = newString(oldString);
std::cout << y[0] << std::endl; //Choosing first character of some c-string